Tuesday, June 7, 2011

POLYMERS

What is said to be polymers?

Polymers are large molecule (macromolecule) composed of repeating structural units. These subunits are typically connected by covalent chemical bonds.


Naturally occurring polymers

few examples of naturally occurring polymers are as follows :
  • cellulose
  • starch
  • protein
  • wool
  • silk
  • natural rubber

Synthetic polymers and its monomers and also its uses


Some Common Addition Polymers

Name(s)

Formula

Monomer

Properties

Uses

Polyethylene
low density (LDPE)
–(CH2-CH2)nethylene
CH2=CH2
soft, waxy solidfilm wrap, plastic bags
Polyethylene
high density (HDPE)
–(CH2-CH2)nethylene
CH2=CH2
rigid, translucent solidelectrical insulation
bottles, toys
Polypropylene
(PP) different grades
–[CH2-CH(CH3)]npropylene
CH2=CHCH3
atactic: soft, elastic solid
isotactic: hard, strong solid
similar to LDPE
carpet, upholstery
Poly(vinyl chloride)
(PVC)
–(CH2-CHCl)nvinyl chloride
CH2=CHCl
strong rigid solidpipes, siding, flooring
Poly(vinylidene chloride)
(Saran A)
–(CH2-CCl2)nvinylidene chloride
CH2=CCl2
dense, high-melting solidseat covers, films
Polystyrene
(PS)
–[CH2-CH(C6H5)]nstyrene
CH2=CHC6H5
hard, rigid, clear solid
soluble in organic solvents
toys, cabinets
packaging (foamed)
Polyacrylonitrile
(PAN, Orlon, Acrilan)
–(CH2-CHCN)nacrylonitrile
CH2=CHCN
high-melting solid
soluble in organic solvents
rugs, blankets
clothing
Polytetrafluoroethylene
(PTFE, Teflon)
–(CF2-CF2)ntetrafluoroethylene
CF2=CF2
resistant, smooth solidnon-stick surfaces
electrical insulation
Poly(methyl methacrylate)
(PMMA, Lucite, Plexiglas)
–[CH2-C(CH3)CO2CH3]nmethyl methacrylate
CH2=C(CH3)CO2CH3
hard, transparent solidlighting covers, signs
skylights
Poly(vinyl acetate)
(PVAc)
–(CH2-CHOCOCH3)nvinyl acetate
CH2=CHOCOCH3
soft, sticky solidlatex paints, adhesives
cis-Polyisoprene
natural rubber
–[CH2-CH=C(CH3)-CH2]nisoprene
CH2=CH-C(CH3)=CH2
soft, sticky solidrequires vulcanization
for practical use
Polychloroprene (cis + trans)
(Neoprene)
–[CH2-CH=CCl-CH2]nchloroprene
CH2=CH-CCl=CH2
tough, rubbery solidsynthetic rubber
oil resistant



Properties of synthetic polymers and methods to overcome the pollution cause by it

Synthetic polymers are very stable and do not corrode. Unfortunately, this also means that it is arduous to dispose. Due to their non biodegradable properties , they may cause pollution, blockage of drainage systems and flash floods. When synthetic polymers are burn, they lug out harmful and poisonous gases and also pungent smell to the air.

Methods to overcome the pollution is simple. All of us, as a continuous consumers should act in a civil way of disposing the synthetic polymers. We should reduce, reuse and recycle as much as possible and we should also find alternative to synthetic polymers. Other than that, the usage of biodegradable synthetic polymers must be encourage and expose to the society.




1 comment:

  1. I just love seeing the advances that science can make. Recently I have been reading up on the pretty impressive thing synethics like PEGylated Polymers / can make and what they can do.

    ReplyDelete